The best approach in proving the Imamate of Imam Ali (as) for followers of the Sunni school of thought is through means of what has been mentioned in the Quran and narrations which have been mentioned in their own sources. In order to do this, one should thoroughly understand that which is presented in verses of the Quran. Meaning, the content of the verse, the context in which it is introduced, instances it refers to, etc. should all be considered in detail.
In the Holy Quran there are many verses which make reference to and establish the Imamate of Ali (as) and the other Imams. Concerning what has been mentioned in these verses, (To see why the name of Imams are not mentioned explicitly in Quran please refer to the subject: The name of Imams (AS) in Quran) there are innumerable narrations from the Holy Prophet (pbuh) which expand further on the circumstances surrounding the revelation of these verses and their details. These narrations are considered authentic by both the Shia and Sunni schools of thought.
The follow are a few of those verses and the appropriate narrations concerning them: (For more information please refer to the subject: The reasons to believe Imamate and Imams)
1. The Verse of Tabligh (propagation): “O Apostle! Communicate that which has been sent to you from your Lord, and if you do not, you will not have communicated His message, and Allah shall protect you from the people. Indeed Allah does not guide the faithless lot.” (Maedeh 67 for more information refer to the subject: Sunnis and the verse “Tabligh”)
In this verse, God ordered the Prophet (pbuh) to communicate his message to the people with heavy emphasis. According to narrations, this verse was revealed in a place by the name of “Ghadir Khum”. In this place, the Prophet (pbuh) publically announced Ali (as) as his successor and the first Imam. (Makarem Shirazi, the message of Quran, vol. 9, Imamate in Quran, from page 182 on.) The event of Ghadir took place in the last year of the Holy Prophet’s life during the time of Hajjatul Vida (the Prophet’s final Hajj) where he stated: “من کنت مولاه فهذا علی مولاه…”, meaning, “For whomever I am his master, Ali is master…”.
This event has been narrated by 110 companions of the Prophet (pbuh), (Abu saeed Khadri, Zein Al din Argham, Jaber bin Abdullah Ansari, Ibn Abbas, Bara bin Aazeb, Hazifeh, Abu harireh, Ibn Masoud and Amer bin Laili.) 84 tabiyin (those who have been informed through intermediaries), and 36 scholars and writers. Allameh Amini, in his book Sharife al-Ghadir, has mentioned all of these narrations with cogent evidence from Islamic sources (authenticated by both the Shia and Sunni schools of thought).
2. The Verse Wilayah: “Your guardian is only Allah, His Apostle, and the faithful who maintain the prayer and give the zakat while bowing down.” (Maedeh 55)
Many interpreters and narrators maintain that this verse was revealed in regards to the elevated status of Imam Ali (as).
Suiti (a Sunni scholar), narrates from the book Dar al-Mansour (a book containing commentary of the Quran), quoting Ibn Abbas who narrates: “Ali (as) was in the ruku of his prayer when a beggar came along asking for help. Ali (as) then proceeded (as) to give the ring on his hand to the beggar as charity. The Prophet (pbuh) asked the beggar, “Who gave you this ring as charity?” He pointed towards Ali (as) and said, “That man who is in ruku did.” At that moment, the verse mentioned above was revealed. (Aldorr Almanthour, vol. 2 page 293)
This narration has also been authenticated by the Sunni scholars Wahedi (Asbab Al Nozool page 148) and Zamkhashari, (Tafsir Keshaf vol. 1, page 649) maintaining that the mentioned verse was revealed in regards to Ali (as).
In his commentary, Fakhr Radhi narrates from Abdullah bin Salaam that: “When this verse was revealed, I said to the Prophet of God (pbuh) that I saw with my own eyes that Ali (as), while in ruku, gave his ring as charity to a needy person. For this reason we accept his wilayah!” In another narration, he also quotes Abuzar who narrates the same occurrences surrounding the revelation of this verse.” (Tafsir of Fakhr Razi)
In his tafsir, Tabari cites many narrations associated with this verse and the circumstances surrounding its revelation. A majority of those narrations affirm that the verse was revealed in regards to Imam Ali (as). (Tabari Tafsir, vol. 6, page 186)
In his book al-Ghadir, the late Allamah Amini has quoted this verse and its association with Imam Ali (as), citing narrations found in approximately twenty Sunni books of narrations (along with their specific chains of narration and sources). (Alghadir, vol. 2, page 52, 53)
It is in this verse that the wilayah of Imam Ali (as) is mentioned alongside that of Allah and the Holy Prophet (pbuh).
3. The Verse of Ulil-amr: “O you who have faith! Obey Allah and obey the Apostle and those vested with authority among you. And if you dispute concerning anything, refer it to Allah and the Apostle, if you have faith in Allah and the Last Day. That is better and more favorable in outcome.” (Nesa 59)
Scholars (There are tens of hadiths in sources of house hold of the prophet below this verse: The mentioned verse has been descended for Ali (AS) and other Imams even in some verses the names of twelve Imams have been mentioned one by one. Borhan Tafsir vol. 1, page 381 – 387.) have stated that this verse has been revealed in reference to Imam Ali (as).
For example Hakem Haskani Hanafi Neishabouri (a renowned Sunni interpreter of the Quran) has quoted five narrations for this verse, and of which associate the title of “Ulil-amr” with Imam Ali (as). (Shavahed al Tanzil vol. 1, page from 148 to 151.)
The commentary of al-Bahr al-Muhit, written by Abuhayan Andulusi Maghribi, quotes Muqatil, Meimoun, and Kalbi (all interpreters of the Quran) who agree that this verse is in reference to the Imams (as) from the household and lineage of the Prophet (pbuh). (Bahr Al Mohit. Vol. 3, page 425)
In his book Eteghad, Abu Bakr bin Mumin Shirazi (a Sunni scholar), quotes Ibn Abbas who affirms that the above verse was revealed in regards to Imam Ali (as). (Ihqaqul-Haqq, vol. 3, page 425)
In brief, this verse informs mankind of its obligation in obeying God, the Prophet (pbuh), and the Ulil-amr. Since this order has been made wajib (obligatory) to the highest degree, it can be inferred that the Ulil-amr, like God and his Prophet (pbuh), should also possess infallibility. Considering what has been mentioned in narrations, this could only be in reference to the infallible twelver Shia Imams (as).
What has been mentioned here, are only a few of the authentic narrations found in Sunni books and three verses found in Shia books regarding the Wilayah and Imamate of Ali (as). There is an abundance of other topics and points to be discovered in many Shia and Sunni books alike. For further information, one should refer to these reliable sources.
In addition to the three verses which have been mentioned, there are others which directly establish the Wilayah and Imamate of Ali (as) and the other Imams (as). The following are a couple of those verses: The verse of Sadiqin which reads “O you who have faith! Be wary of Allah and be with the Truthful.” (Tobeh, 119, we have in hadiths that: what is meant by “true in words and deeds” are Ali (AS) and house hold of the prophets. (Yanabe al Mavadat page 115 and Shavahed al Tanzil vol. 1 page 626)) and the verse of Gurba which reads “That is of which Allah gives the good news to His servants, (to) those who believe and do good deeds. Say: I do not ask of you any reward for it but love for my near relatives; and whoever earns good, We give him more of good therein; surely Allah is Forgiving, Grateful.” (Shora 33, for more information, refer to subject: The house hold of the prophet (PBUH) and the verse Mawaddah.) These verses, in addition to narrations from the Holy Prophet (pbuh), can be found in both Shia and Sunni sources.
Besides the mentioned verses, there are others which highlight the virtues and qualities of Imam Ali (as) and depict his superiority in comparison to the other companions and supporters of the Holy Prophet (pbuh). Logically speaking, it is absurd to select that which is inferior as opposed to that which is superior. Therefore, it is only was rational for Ali (as) to succeed the Holy Prophet (pbuh) and take his rightful role as Imam. For further information on this matter, you may refer to volume nine (Imamate and Leadership in the Holy Quran, page 177 and on) of Ayatollah Makarem Shirazi’s commentary of the Holy Quran. (Islamquest)